A powerful method for In Situ and rapid detection of trace nanoplastics in water-Mie scattering.

The pervasive presence of nanoplastics (NPs) in environmental media has raised significant concerns regarding their implications for environmental safety and human health. However, owing to their tiny size and low level in the environment, there is still a lack of effective methods for measuring the amount of NPs. Leveraging the principles of Mie scattering, a novel approach for rapid in situ quantitative detection of small NPs in low concentrations in water has been developed. A limit of detection of 4.2 µg/L for in situ quantitative detection of polystyrene microspheres as small as 25 nm was achieved, and satisfactory recoveries and relative standard deviations were obtained. The results of three self-ground NPs showed that the method can quantitatively detect the concentration of NPs in a mixture of different particle sizes. The satisfactory recoveries (82.4% to 110.3%) of the self-ground NPs verified the good anti-interference ability of the method. The total concentrations of the NPs in the five brands of commercial bottled water were 0.07 to 0.39 µg/L, which were directly detected by the method. The proposed method presents a potential approach for conducting in situ and real-time environmental risk assessments of NPs on human and ecosystem health in actual water environments.

Occurrence and distribution of lipophilic marine algal toxins in the coastal seawater of Southeast China and the South China Sea.

The composition, levels, and spatial distribution of dissolved lipophilic marine algal toxins (LMATs) including cyclic imines (CIs), yessotoxins (YTXs), okadaic acid (OA) and its derivatives, pectenotoxins (PTXs), azaspiracids (AZAs), and brevetoxins (BTXs) in the coastal waters of Southeast China (Xiamen) and the South China Sea (Hainan Island and Beibu Gulf) were investigated and compared for the first time. Dissolved AZA3 was firstly detected in the coastal seawater of China. OA and PTX2 were widely distributed in the three areas studied. Gymnodimine (GYM), 13-desmethyl spirolide C (SPX1), YTX, and homo-yessotoxins (h-YTX) were found mainly in the South China Sea. The average ∑LMAT concentrations in the coastal waters of Xiamen, Hainan Island, and Beibu Gulf were 10.02 ng/L, 4.21 ng/L, and 44.27 ng/L, respectively. More groups and much higher concentrations of LMATs occurred in the South China Sea than that in the other sea areas of China.